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A Nonionic Alcohol Soluble Polymer Cathode Interlayer Enables Efficient Organic and Perovskite Solar Cells

Anirudh Sharma, Saumya Singh, Xin Song, Diego Rosas Villalva, Joel Troughton, Daniel Corzo, Levent Toppare, Görkem Günbaş, Bob C. Schroeder, Derya Baran

2021Chemistry of Materials55 citationsDOIOpen Access PDF

Abstract

, enabling its use as a CIL with a film thickness of up to ∼35(±2) nm. Utilizing the new CIL, 16% power conversion efficiency (PCE) is achieved for organic solar cells (OSCs) based on the PM6-Y6 photoactive layer (8.9% PCE for no CIL and 15.1% with state-of-the-art CIL, PDINO), and perovskite solar cells from methylammonium lead iodide yielded a PCE of 17.6%. Compared to the reference devices, the new CIL reduced trap-assisted carrier recombination and increased the built-in potential by 80 mV, simultaneously enhancing all photovoltaic parameters. Moreover, new CIL based devices had better photostability with no burn-in losses.

Topics & Concepts

CathodeMaterials scienceCompatibility (geochemistry)PolymerPerovskite (structure)Photoactive layerSolar cellLayer (electronics)Chemical engineeringOrganic solar cellOptoelectronicsNanotechnologyComposite materialChemistryPhysical chemistryEngineeringOrganic Electronics and PhotovoltaicsConducting polymers and applicationsPerovskite Materials and Applications
A Nonionic Alcohol Soluble Polymer Cathode Interlayer Enables Efficient Organic and Perovskite Solar Cells | Litcius