Mechanistic Insight into Concerted Proton–Electron Transfer of a Ru(IV)-Oxo Complex: A Possible Oxidative Asynchronicity
Hiroaki Kotani, Hinatsu Shimomura, Kei Ikeda, Tomoya Ishizuka, Yoshihito Shiota, Kazunari Yoshizawa, Takahiko Kojima
Abstract
as a dominant reactive species.
Topics & Concepts
ChemistryElectron transferProtonProton-coupled electron transferRedoxConcerted reactionKinetic isotope effectReaction rate constantMedicinal chemistryKineticsPhotochemistryInorganic chemistryCatalysisOrganic chemistryPhysicsDeuteriumQuantum mechanicsMetal-Catalyzed Oxygenation MechanismsMetal complexes synthesis and propertiesPorphyrin and Phthalocyanine Chemistry