Electrochemically mediated synthesis of trifluoromethylallenes
Jialan Zhang, Jin-Xiu Xiong, Lu‐Qi Fei, Fei‐Hu Cui, Shu‐Hui Li, Haitao Tang, Yan-Zhao Xie, Ying‐Ming Pan
Abstract
Herein, we report electrochemically mediated trifluoromethylallene synthesis via the rearrangement of trifluoromethyl-containing 1,3-enynes under the action of silicon or boron radicals, with good selectivity and without external oxidants.
Topics & Concepts
ChemistryCombinatorial chemistryFluorine in Organic Chemistry