The structures of ordered defects in thiocyanate analogues of Prussian Blue
Matthew J. Cliffe, Evan N. Keyzer, Andrew D. Bond, Maxwell A. Astle, Clare P. Grey
Abstract
antisite defects, water substitution for thiocyanate, adventitious extra-framework cations and reduced metal coordination number. These materials provide an unusually clear view of defects in molecular framework materials and their variety suggests that similar richness may be waiting to be uncovered in other hybrid perovskite frameworks.
Topics & Concepts
Prussian blueThiocyanateChemistryCrystallographyStereochemistryMaterials scienceInorganic chemistryElectrodePhysical chemistryElectrochemistrySolid-state spectroscopy and crystallography