Synthesis and Properties of Polymers Based on N-Vinyl-Pyrrolidone and Halogen-Containing Compounds of Acrylic Acids
Yusuf A. Malkanduev, М. Б. Бегиева, A.A. Kokoevа, Muslim Mikitaev, Аblulakhat T. Dzhalilov, M. K. Vindizheva
Abstract
The paper presents the results of the copolymerization of α-halogens of acrylic acid and N-vinylpyrrolidone in the presence of a radical initiator. The copolymerization equations are presented and activity factors are calculated. IR spectra of the obtained copolymers confirm the amination reaction. The synthesized aminated polymers form intramuscular compounds with divalent metal halides at room temperature. The kinetics of the copolymerization reaction of these systems shows that the presence of a reactive halogen atom in the structure of the copolymer has a great influence on the formation and properties of the copolymers.
Topics & Concepts
CopolymerHalogenPolymer chemistryAcrylic acidPolymerHalideChemistryMaterials scienceAminationAtom-transfer radical-polymerizationCatalysisOrganic chemistryAlkylAdvanced Polymer Synthesis and CharacterizationInorganic and Organometallic ChemistryChemical Reactions and Mechanisms