On the stratospheric chemistry of midlatitude wildfire smoke
Susan Solomon, Kimberlee Dubé, Kane A. Stone, Pengfei Yu, Douglas E. Kinnison, O. B. Toon, S. E. Strahan, Karen H. Rosenlof, R. W. Portmann, Sean Davis, William J. Randel, P. F. Bernath, C. D. Boone, Charles Bardeen, Adam Bourassa, Daniel Zawada, D. A. Degenstein
Abstract
Significance Large wildfires have been observed to inject smoke into the stratosphere, raising questions about their potential to affect the stratospheric ozone layer that protects life on Earth from biologically damaging ultraviolet radiation. Multiple observations of aerosol and NO 2 concentrations from three independent satellite instruments are used here together with model calculations to identify decreases in stratospheric NO 2 concentrations following major Australian 2019 through 2020 wildfires. The data confirm that important chemistry did occur on the smoke particle surfaces. The observed behavior in NO 2 with increasing particle concentrations is a marker for surface chemistry that contributes to midlatitude ozone depletion. The results indicate that increasing wildfire activity in a warming world may slow the recovery of the ozone layer.