General and practical intramolecular decarbonylative coupling of thioesters <i>via</i> palladium catalysis
Han Cao, Xuejing Liu, Fusheng Bie, Yijun Shi, Ying Han, Peng Yan, Michal Szostak, Chengwei Liu
Abstract
We report a general and practical palladium-catalyzed intramolecular decarbonylative coupling of thioesters <italic>via</italic> C–S bond cleavage, decarbonylation and C–S bond reformation.
Topics & Concepts
DecarbonylationIntramolecular forceChemistryPalladiumCatalysisBond cleavageCleavage (geology)Coupling (piping)Medicinal chemistryStereochemistryOrganic chemistryMechanical engineeringEngineeringFracture (geology)Geotechnical engineeringSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling Reactions