Constructing a Type-II CdS/Bi<sub>2</sub>MoO<sub>6</sub> Heterostructure: Promoting Photocatalytic Degradation of Contaminants
Feng Lijuan, Lili Ai, Luxiang Wang, Nannan Guo, Mengjiao Xu, Changyu Leng, Qingtao Ma, Chuan Tan, Haolan Shi
Abstract
Constructing a heterostructure is regarded as one of the most favorable approaches to attaining the separation ability of photogenerated carriers and strengthening photocatalysis efficiency. In this study, a CdS/Bi 2 MoO 6 type-II heterostructure was constructed through a hydrothermal technique. The photocatalytic test result shows that the degradation efficiency of rhodamine B (RhB) and tetracycline (TC) over CS/BMO-1 was 100 and 92% under visible light, respectively, which is the highest compared to other samples. The exceptional photocatalytic efficiency is principally associated with generating an inherent electric field within a type-II heterostructure, effectively restraining the recombination of photogenerated electron hole pairs. The intermediate products during the photocatalytic degradation of RhB and TC were identified through liquid chromatography–mass spectrometry, and the hypotheses were formulated regarding the corresponding photodegradation mechanisms. Furthermore, the outcomes of capture tests exhibited that the primary active species were • O 2 – and h +, and a mechanism of the photocatalytic degradation procedure has been proposed.