Thiocyanate-Stabilized Pseudo-cubic Perovskite CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub> from Coincident Columnar Defect Lattices
Takuya Ohmi, Iain W. H. Oswald, James R. Neilson, Nikolaj Roth, Shunta Nishioka, Kazuhiko Maeda, Kotaro Fujii, Masatomo Yashima, Masaki Azuma, Takafumi Yamamoto
Abstract
α-FAPbI 3 (FA + = CH(NH 2 ) 2 + ) with a cubic perovskite structure is promising for photophysical applications. However, α-FAPbI 3 is metastable at room temperature, and it transforms to the δ-phase at a certain period of time at room temperature. Herein, we report a thiocyanate-stabilized pseudo-cubic perovskite FAPbI 3 with ordered columnar defects (α′-phase). This compound has a √5 a p × √5 a p × a p tetragonal unit cell ( a p: cell parameter of primitive perovskite cell) with a band gap of 1.91 eV. It is stable at room temperature in a dry atmosphere. Furthermore, the presence of the α′-phase in a mixed sample with the δ-phase drastically reduces the δ-to-α transition temperature measured on heating, suggesting the reduction of the nucleation energy of the α-phase or thermodynamic stabilization of the α-phase through epitaxy. The defect-ordered pattern in the α′-phase forms a coincidence-site lattice at the twinned boundary of the single crystals, thus hinting at an epitaxy- or strain-based mechanism of α-phase formation and/or stabilization. In this study, we developed a new strategy to control defects in halide perovskites and provided new insight into the stabilization of α-FAPbI 3 by pseudo-halide and grain boundary engineering.