The multifunctional design of metal–organic framework by applying linker desymmetrization strategy: synergistic catalysis for high CO<sub>2</sub>-epoxide conversion
Yueying Zhu, Jiaming Gu, Xueyue Yu, Borong Zhang, Guanghua Li, Jiantang Li, Yunling Liu
Abstract
A novel copper-organic framework was synthesized by a linker desymmetrization strategy. Synergistic catalysis with Lewis and Brønsted acid sites promoted a high catalytic efficiency towards the CO 2 -propylene oxide cycloaddition reaction.
Topics & Concepts
DesymmetrizationEpoxideCatalysisCycloadditionLinkerChemistryPropylene oxideBrønsted–Lowry acid–base theoryLewis acids and basesOxideOrganic chemistryCombinatorial chemistryEnantioselective synthesisPolymerComputer scienceOperating systemCopolymerEthylene oxideMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisChemical Synthesis and Reactions