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High-Stability RuO<sub>2</sub>/MoO<sub>3</sub> Electrocatalyst for the Oxygen Evolution Reaction in Proton-Exchange-Membrane Water Electrolysis

Wenqing Ren, Kaixin Wang, Dan Lu, Chenxi Xu

2023ACS Applied Energy Materials13 citationsDOI

Abstract

The slow kinetics and low durability of catalysts in the oxygen evolution reaction (OER) have been long-standing issues. The scarcity and high cost of iridium have posed limitations on its widespread implementation. Therefore, a noniridium catalyst with high activity and stability is the key for proton-exchange-membrane water electrolysis. This work reports a high activity and stability RuO 2 /MoO 3 catalyst for water electrolysis. The catalyst exhibits an oxygen evolution reaction (OER) performance with an overpotential of 267 mV at 10 mA cm –2 and demonstrates outstanding long-term stability. Moreover, the PEMWE cell-based RuO 2 /MoO 3 anode achieves an overpotential of 0.777 V at 2 A cm –2 and high stability for 12 h at 1 A cm –2 .

Topics & Concepts

OverpotentialOxygen evolutionElectrocatalystElectrolysis of waterCatalysisElectrolysisWater splittingProton exchange membrane fuel cellAnodeChemistryInorganic chemistryChemical engineeringOxygenMaterials scienceElectrochemistryElectrodePhysical chemistryPhotocatalysisOrganic chemistryEngineeringElectrolyteElectrocatalysts for Energy ConversionFuel Cells and Related MaterialsAmmonia Synthesis and Nitrogen Reduction