Monolithic Photoelectrochemical CO<sub>2</sub> Reduction Producing Syngas at 10% Efficiency
Tobias A. Kistler, Min Young Um, Jason K. Cooper, Ian D. Sharp, Peter Agbo
Abstract
Abstract Increasing anthropogenic carbon dioxide emissions have prompted the search for photoelectrochemical (PEC) methods of converting CO 2 to useful commodity products, including fuels. Ideally, such PEC approaches will be sustained using only sunlight, water, and CO 2 as energetic and reactant inputs. However, low peak conversion efficiencies (<5%) have made commercialization of fully‐integrated PEC devices prohibitive. Here, a 4 cm 2 monolithic PEC device exceeding 10% solar‐to‐fuel efficiency with principal fuel products of carbon monoxide and hydrogen is reported. The corresponding solar‐to‐CO and solar‐to‐H 2 efficiencies are 7% and 3.5%, respectively. Screening of a range of operating conditions reveals a tunable product mixture of H 2 and CO using a gold electrocatalyst. Accordingly, it is shown that device optimization yields a H 2 ‐to‐CO ratio of 1:2 commonly present in synthesis gas (syngas). Notably, the modularity and facile fabrication of this device permit the incorporation of a broad array of materials for various applications. For example, the electrocatalyst may easily be swapped to target a different set of products.