Electron-donor–acceptor (EDA) complex-driven regioselective vicinal and oxidative geminal functionalization of alkynes
Dinabandhu Barik, Nikita Chakraborty, Ashish Kumar Sahoo, Hirendra Nath Dhara, Bhisma K. Patel
Abstract
A visible-light-initiated EDA complex-driven regioselective vicinal and oxidative geminal thiosulfonylation of alkynes under solvent and base switchable conditions is presented.
Topics & Concepts
GeminalVicinalRegioselectivitySurface modificationChemistryAcceptorOxidative phosphorylationElectron acceptorCombinatorial chemistryPhotochemistryOrganic chemistryCatalysisPhysicsCondensed matter physicsBiochemistryPhysical chemistryCatalytic C–H Functionalization MethodsSulfur-Based Synthesis TechniquesRadical Photochemical Reactions