Fenton-like chemistry enables catalytic oxidative desulfurization of thioacetals and thioketals with hydrogen peroxide
Guodong Zhao, Yaxin Wang, Cheng Wang, Haimin Lei, Bingqing Yi, Rongbiao Tong
Abstract
The catalytic deprotection of thioacetals/thioketals with Fenton-halide [H 2 O 2 /CeBr 3 (cat)]: reactive brominating species (RBS) generated in situ from Fenton-like chemistry are highly effective for the oxidative desulfurization of thioacetals and thioketals.
Topics & Concepts
Flue-gas desulfurizationHydrogen peroxideChemistryCatalysisOxidative phosphorylationHalideOrganic chemistryCombinatorial chemistryBiochemistryChemical Synthesis and ReactionsSulfur-Based Synthesis TechniquesPolyoxometalates: Synthesis and Applications