Resolving Halide Ion Stabilization through Kinetically Competitive Electron Transfers
Alexander M. Deetz, Gerald J. Meyer
Abstract
is a poor indicator of these reduction potential shifts. Furthermore, the historic and widely used assumption that Coulombic interactions alone are responsible for stabilization must be reconsidered, at least for polarizable halogens.
Topics & Concepts
HalideChemistryHalogenPhotochemistryIonAcetonitrileElectron transferQuenching (fluorescence)Inorganic chemistryPhysical chemistryComputational chemistryOrganic chemistryFluorescenceQuantum mechanicsPhysicsAlkylRadical Photochemical ReactionsElectrochemical Analysis and ApplicationsCO2 Reduction Techniques and Catalysts