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The Human Host‐Defense Peptide Cathelicidin LL‐37 is a Nanomolar Inhibitor of Amyloid Self‐Assembly of Islet Amyloid Polypeptide (IAPP)

Valentina Armiento, Kathleen Hille, Denise Naltsas, Jennifer S Lin, Annelise E. Barron, Aphrodite Kapurniotu

2020Angewandte Chemie International Edition50 citationsDOIOpen Access PDF

Abstract

Amyloid self-assembly of islet amyloid polypeptide (IAPP) is linked to pancreatic inflammation, β-cell degeneration, and the pathogenesis of type 2 diabetes (T2D). The multifunctional host-defence peptides (HDPs) cathelicidins play crucial roles in inflammation. Here, we show that the antimicrobial and immunomodulatory polypeptide human cathelicidin LL-37 binds IAPP with nanomolar affinity and effectively suppresses its amyloid self-assembly and related pancreatic β-cell damage in vitro. In addition, we identify key LL-37 segments that mediate its interaction with IAPP. Our results suggest a possible protective role for LL-37 in T2D pathogenesis and offer a molecular basis for the design of LL-37-derived peptides that combine antimicrobial, immunomodulatory, and T2D-related anti-amyloid functions as promising candidates for multifunctional drugs.

Topics & Concepts

CathelicidinIsletAmyloid (mycology)PathogenesisPeptideInflammationCell biologyAntimicrobial peptidesBiologyChemistryBiochemistryImmunologyDiabetes mellitusEndocrinologyBotanyAntimicrobial Peptides and ActivitiesPeptidase Inhibition and AnalysisGlycosylation and Glycoproteins Research
The Human Host‐Defense Peptide Cathelicidin LL‐37 is a Nanomolar Inhibitor of Amyloid Self‐Assembly of Islet Amyloid Polypeptide (IAPP) | Litcius