Mechanistic study of C–H bond activation by O<sub>2</sub> on negatively charged Au clusters: α,β-dehydrogenation of 1-methyl-4-piperidone by supported Au catalysts
Ray Miyazaki, Xiongjie Jin, Daichi Yoshii, Takafumi Yatabe, Tomohiro Yabe, Noritaka Mizuno, Kazuya Yamaguchi, Jun‐ya Hasegawa
Abstract
Aerobic C–H activation by Au/OMS-2 catalyst is driven by charge transfer from OMS-2 to adsorbed O<sub>2</sub><italic>via</italic> Au cluster.
Topics & Concepts
DehydrogenationCatalysisChemistryCluster (spacecraft)AdsorptionPhotochemistryPhysical chemistryOrganic chemistryProgramming languageComputer scienceAsymmetric Hydrogenation and CatalysisNanocluster Synthesis and ApplicationsCatalytic C–H Functionalization Methods