Strongly visible light-absorbing metal–organic frameworks functionalized by cyclometalated ruthenium(<scp>ii</scp>) complexes
Eirik Mydske Thoresen, Sigurd Øien‐Ødegaard, Gurpreet Kaur, Mats Tilset, Karl Petter Lillerud, Mohamed Amedjkouh
Abstract
The metal–organic framework (MOF) UiO-67 was functionalized by incorporating different cyclometalated ruthenium(<sc>ii</sc>) complexes using three different methods: premade linker synthesis, postsynthetic functionalization, and postsynthetic linker exchange.
Topics & Concepts
RutheniumMetalChemistryVisible spectrumMetal-organic frameworkPhotochemistryCombinatorial chemistryPolymer chemistryMaterials scienceOrganic chemistryCatalysisOptoelectronicsAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesNanocluster Synthesis and Applications