Electrochemical synthesis of γ-keto sulfones containing a β-quaternary carbon center <i>via</i> 1,2-migration
Wen Xia, Yawen Yang, Xiaohui Zhang, Liangzhen Hu, Yan Xiong
Abstract
An electrochemical method has been developed for the synthesis of γ-keto sulfones with a β-quaternary carbon center through 1,2-C migration mediated by sulfonyl under metal- and oxidant-free conditions.
Topics & Concepts
ElectrochemistryQuaternary carbonSulfonylQuaternaryCarbon fibersChemistryCenter (category theory)MetalCombinatorial chemistryMaterials scienceOrganic chemistryCatalysisElectrodeEnantioselective synthesisCrystallographyPhysical chemistryBiologyComposite numberPaleontologyAlkylComposite materialSulfur-Based Synthesis TechniquesRadical Photochemical ReactionsCatalytic C–H Functionalization Methods