MOF-Zn-NHC as an efficient N-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids <i>via</i> a cooperative geminal anomeric based oxidation
Saeed Babaee, Mahmoud Zarei, Mohammad Ali Zolfigol
Abstract
an anomeric based oxidation. Features such as mild reaction conditions and no need for a co-catalyst or oxidative reagent can be considered as the major advantages of the presented method in this study.
Topics & Concepts
GeminalCarbeneCatalysisChemistryAnomerOrganic chemistryMedicinal chemistryPolymer chemistryCombinatorial chemistryN-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic Cross-Coupling ReactionsCarbon dioxide utilization in catalysis