Plasma-Induced Interfacial Processes in Metal Halides FTIR Gas Cell Windows
Jaka Olenik, Vasyl Shvalya, Martina Modic, Jernej Ekar, Janez Kovač, Uroš Cvelbar, James L. Walsh
Abstract
Abstract Fourier transform infrared spectroscopy (FTIR) is one of the most widely used vibrational diagnostic techniques to investigate gas-phase reactive oxygen and nitrogen species (RONS). However, the technique carries intrinsic challenges, particularly in relation to interfering peaks in the spectral data. This study explores the interfacial processes that occur when reactive oxygen and nitrogen species generated by a non-equilibrium air plasma interact with the metal halide windows of an FTIR gas cell, leading to the appearance and evolution of spurious absorption peaks which complicate spectral interpretation. Raman spectroscopy, X-ray photoelectron spectroscopy, time of flight secondary ion mass spectrometry and attenuated total reflectance-FTIR spectroscopy were used to elucidate the origin of spurious absorption peaks spanning the 1400–1300 cm −1 spectral range as a result of KBr exposure to plasma generated species. It was found that plasma exposed KBr contained a lower atomic fraction of Br which was replaced by the NO 3 nitrate group, the main absorbance peak of which progressively evolved with plasma exposure and affected the window transparency over the corresponding FTIR region. A correlation was revealed between KNO 3 formation, plasma power and exposure time to a growth and change in molecular vibrational energies corresponding to asymmetric NO 3 stretching vibrations in the KNO 3 structure.