Adsorption thermodynamics and kinetics of hydrochloric-acid-modified bentonite for Zn(II) in wastewater
Xiumin Yang, Fujun Zhao
Abstract
In order to study the Zn(II) adsorption characteristics of hydrochloric-acid-modified bentonite in wastewater, physical characterization of hydrochloric-acid-modified bentonite was carried out, the effects of the initial concentration, reaction time, and temperature on the Zn(II) adsorption were investigated, and the adsorption kinetics and thermodynamic mechanism of the hydrochloric-acid- modified bentonite adsorption of Zn(II) were examined. The results showed that hydrochloric acid modification increased the interlayer spacing of the bentonite, and the structure of the binding between slices became looser. Hydrochloric acid modification altered the hydroxyl groups on the bentonite surface, and the hydrophilicity was enhanced. The Zn(II) adsorption capacities of bentonite and hydrochloric-acid-modified bentonite increased with the increase in the initial Zn(II) concentration, and the adsorption followed the Langmuir and Freundlich equations. The thermodynamic parameters suggested that the adsorption of Zn(II) was an endothermic, spontaneous, and entropy-increasing process. The adsorption basically reached equilibrium within 120 min, and the adsorption followed the quasi-second-order adsorption kinetic equation. The adsorption process was mainly chemical adsorption, and the intra-particle diffusion process was not the only step controlling the adsorption rate. This study provides a theoretical basis for the remediation of toxic metal wastewater and contaminated soil.