A [Pd<sub>2</sub>L<sub>4</sub>]<sup>4+</sup>cage complex for<i>n</i>-octyl-β-<scp>d</scp>-glycoside recognition
Xander Schaapkens, Eduard O. Bobylev, Joost N. H. Reek, Tiddo J. Mooibroek
Abstract
The cage complex [Pd294]4+ (3') binds n-octyl glycosides in DCM/DMSO (9 : 1) solution with Ka ≈ 51 M-1 for n-Oct-β-d-Glc and Ka ≈ 29 M-1 for n-Oct-β-d-Gal.
Topics & Concepts
GlycosideChemistryStereochemistryCrystallographyCombinatoricsMathematicsCarbohydrate Chemistry and SynthesisGlycosylation and Glycoproteins ResearchMetal-Organic Frameworks: Synthesis and Applications