Stereospecific Isomerization of Allylic Halides via Ion Pairs with Induced Noncovalent Chirality
Samuel Martinez‐Erro, Víctor García‐Vázquez, Amparo Sanz‐Marco, Belén Martín‐Matute
Abstract
ratios. Furthermore, the [1,3]-proton shift takes place with an outstanding level of chirality transfer from chiral allylic alcohols (≤98%) to give chiral trifluoromethylated vinyl chlorides.
Topics & Concepts
Allylic rearrangementChemistryChirality (physics)IsomerizationStereospecificityHalideRegioselectivityEnantioselective synthesisCatalysisProtonMedicinal chemistryOrganic chemistryPhysicsQuantum mechanicsChiral symmetry breakingQuarkNambu–Jona-Lasinio modelFluorine in Organic ChemistryAsymmetric Synthesis and CatalysisChemical Synthesis and Analysis