Transition metal-free electrocatalytic halodeborylation of arylboronic acids with metal halides MX (X = I, Br) to synthesize aryl halides
Zhengjiang Fu, Guangguo Hao, Yaping Fu, Dongdong He, Xun Tuo, Shengmei Guo, Hu Cai
Abstract
An efficient and regioselective <italic>ipso</italic>-halogenation of diverse arylboronic acids with metal halide salts MX (X = I, Br) has been well established under electrochemical conditions.
Topics & Concepts
HalideChemistryHalogenationArylRegioselectivityTransition metalMetal halidesMetalElectrochemistryMedicinal chemistryOrganic chemistryCatalysisAlkylElectrodePhysical chemistryRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods