Mpemba effect of a mean-field system: The phase transition time
Zhen-Yu Yang, Ji-Xuan Hou
Abstract
The counterintuitive phenomenon-that an initially hotter water freezes faster than initially cooler water-is named the "Mpemba effect." Although it has been known for centuries, the underlying mechanism remains unclear. Recently, the Mpemba effect rekindled the interest of researchers since several studies identified that it might occur in some Markovian systems, and a general statistical-physical Mpemba effect framework was correspondingly proposed. In our previous study [Z.-Y. Yang and J.-X. Hou, Phys. Rev. E 101, 052106 (2020)10.1103/PhysRevE.101.052106], we observed the non-Markovian Mpemba effect in a mean-field system (MFS), where the Mpemba effect originates from the back-reaction of the thermal reservoir. Naturally, the phase transition time is the key to the occurrence of the Mpemba effect, which, however, has not been quantitatively described. Following the direction of previous work, this study rigorously derives the phase transition time under different conditions, and quantitatively describes the mechanism of the non-Markovian Mpemba effect in a MFS. In addition, the validation of our theory was further verified via the microcanonical Monte Carlo simulation. An accurate description of the underlying mechanism of our proposed MFS facilitates the generalization of the Mpemba effect framework in statistical physics and may benefit in answering the riddle of the century, the original Mpemba effect in water.