A hybrid bioinspired catechol-alloxazine triangular nickel complex stabilizing protons and electrons
Agnideep Das, Hannah Jobelius, Jules Schleinitz, Stefani Gamboa-Ramírez, Geordie Creste, Gwendal Kervern, Jésus Raya, Nolwenn Le Breton, Aurélie Guénet, Zahia Boubegtiten-Fezoua, Laurence Grimaud, Maylis Orio, Guillaume Rogez, Petra Hellwig, Sylvie Choua, Sylvie Ferlay, Marine Desage‐El Murr
Abstract
A new class of redox-active ligands merging catechol and alloxazine structures is reported. A trimetallic triangular complex is formed upon complexation to nickel.
Topics & Concepts
CatecholNickelRedoxElectronChemistryMaterials scienceCombinatorial chemistryCrystallographyInorganic chemistryMetallurgyOrganic chemistryPhysicsQuantum mechanicsMagnetism in coordination complexesMetal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal Complexes