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Ultrathin polymethylmethacrylate interlayers boost performance of hybrid tin halide perovskite solar cells

Dong Ding, Luis Lanzetta, Xinxing Liang, Ganghong Min, Marcin Giza, Thomas J. Macdonald, Saif A. Haque

2021Chemical Communications47 citationsDOIOpen Access PDF

Abstract

Introducing a polymethylmethacrylate (PMMA) layer at the (PEA)0.2(FA)0.8SnI3 perovskite/hole transport layer interface leads to a remarkable improvement in the photogenerated current density and fill factor, resulting in an increase in the power conversion efficiency from 6.5% to 10%. PMMA is proposed to mitigate interfacial charge losses and to induce a more favourable distribution of 2D perovskite phases, elucidating a pathway towards the development of high-performance tin-based perovskite solar cells.

Topics & Concepts

Perovskite (structure)HalideTinMaterials scienceEnergy conversion efficiencyLayer (electronics)OptoelectronicsCurrent densityChemical engineeringNanotechnologyInorganic chemistryChemistryMetallurgyQuantum mechanicsPhysicsEngineeringPerovskite Materials and ApplicationsChalcogenide Semiconductor Thin FilmsQuantum Dots Synthesis And Properties
Ultrathin polymethylmethacrylate interlayers boost performance of hybrid tin halide perovskite solar cells | Litcius