Guest-induced pore breathing controls the spin state in a cyanido-bridged framework
Michał Magott, Klaudia Płonka, Barbara Sieklucka, Katarzyna Dziedzic-Kocurek, Wataru Kosaka, Hitoshi Miyasaka, Dawid Pinkowicz
Abstract
), which resulted in a 15% volume increase and stabilization of the HS state in the whole temperature range down to 2 K. The demonstrated post-synthetic guest-exchange employing common gases is an efficient approach for tuning the spin state in breathing SCO-PCPs.
Topics & Concepts
Spin (aerodynamics)MoleculeBreathingCoordination polymerSpin crossoverSpin statesPolymerMaterials scienceChemistryCrystallographyInorganic chemistryPhysicsThermodynamicsOrganic chemistryAnesthesiaMedicineMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research