Chirality–Racemization Strategy Toward Copper (I) Iodide Hybrid Single‐Crystalline Scintillators for X‐Ray Detection and Imaging Applications
Zhexin Song, Zhenglin Jia, Xiaoyu Guo, Binyin Yu, Guokui Liu, Lingqiang Meng, Yucheng Liu, Qianqian Lin, Yangyang Dang
Abstract
Abstract Organic–inorganic hybrid copper(I)‐based halides have attracted great interest in the field of optoelectronics due to their low cost, non‐toxicity, large Stokes shift, and high photoluminescence quantum yields (PLQYs). Here, bulk zero‐dimensional (0D) organic‐inorganic hybrid copper(I)‐based (R,S‐2‐mpip) 2 Cu 2 I 6 (mpip = methylpiperazinium, C 5 H 14 N 2 2+ ) single crystals have been grown with equal stoichiometric ratios of R‐ and S‐2‐mpip ligands by chirality–racemization strategy for the first time. Interestingly, (R,S‐2‐mpip) 2 Cu 2 I 6 single crystals exhibit strong blue–green photoluminescence (PL) located at 520 nm with large Stokes shift of about 230 nm and high PLQY of about 65.96%, which originates from self‐trapped excitons (STEs). More importantly, (R,S‐2‐mpip) 2 Cu 2 I 6 single crystals also exhibit the strong radioluminescence (RL) at 520 nm, the fast X‐ray scintillation response with a light yield of about 47 000 photon MeV −1 and low detection limit of 6.48 nGy air s −1 when exposed to X‐ray irradiation condition, which is superior to that of other copper(I) iodide‐based hybrids. Based on the excellent characteristics, X‐ray imaging systems based on (R,S‐2‐mpip) 2 Cu 2 I 6 single crystals exhibit the clear images of “QFNU” logo and crystal symbol pattern. This work not only deepens the understandings of material design and fundamental properties of these racemate systems, but also provides guidance for the further applications in the multi‐functional optoelectronics.