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Room temperature charge-transfer phosphorescence from organic donor–acceptor Co-crystals

Swadhin Garain, Shagufi Naz Ansari, Anju Ajayan Kongasseri, Bidhan Chandra Garain, Swapan K. Pati, Subi J. George

2022Chemical Science117 citationsDOIOpen Access PDF

Abstract

LE excited state. Through comprehensive spectroscopic, theoretical studies, and single-crystal analyses, we elucidate the unparalleled role of intermolecular donor-acceptor interactions to toggle between the emissive excited states and stabilize the triplet excitons. We envisage that the present study will be able to provide new and innovative dimensions to the existing molecular designs employed for triplet harvesting.

Topics & Concepts

PhosphorescenceExcited stateCrystal engineeringPhotochemistryAcceptorIntermolecular forceChemistryTriplet stateChemical physicsMoleculeSinglet stateSupramolecular chemistryMaterials scienceFluorescenceAtomic physicsOrganic chemistryPhysicsCondensed matter physicsQuantum mechanicsLuminescence and Fluorescent MaterialsOrganic Light-Emitting Diodes ResearchPerovskite Materials and Applications
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