Perchlorate-induced structural diversity in thiosemicarbazone copper(<scp>ii</scp>) complexes provides insights to understand the reactivity in acidic and basic media
Rubén Gil‐García, G. Madariaga, Alondra Jiménez-Pérez, Ignacio Herrán-Torres, Adrián Gago-González, Marı́a Ugalde, Vaidas Januskaitis, Joaquín Barrera-García, Maite Insausti, María S. Galletero, J. Borrás, José V. Cuevas, Rosa Pedrido, P. Gomez-Saiz, Luís Lezama, Javier García‐Tojal
Abstract
Perchlorate ions induce structural diversity in a thiosemicarbazone copper( ii ) system, whose aqueous chemistry includes desulfurization reactions even at physiological pH values.
Topics & Concepts
PerchlorateSemicarbazoneReactivity (psychology)ChemistryCopperCombinatorial chemistryStereochemistryOrganic chemistryIonAlternative medicineMedicinePathologyMetal complexes synthesis and propertiesMolecular Sensors and Ion DetectionChemical Analysis and Environmental Impact