Room-Temperature Spin Crossover in a Solution of Iron(II) Complexes with <i>N</i>,<i>N</i>′-Disubstituted Bis(pyrazol-3-yl)pyridines
Dmitry Yu. Aleshin, Igor A. Nikovskiy, Valentin V. Novikov, Alexander V. Polezhaev, Elizaveta K. Melnikova, Yulia V. Nelyubina
Abstract
'-disubstituted 3-bpp to undergo an almost complete SCO centered at room temperature in a less polar solvent of a high hydrogen-bond acceptor ability.
Topics & Concepts
Spin crossoverChemistrySubstituentPyridineLigand (biochemistry)SolventPolar effectPolarSpin statesHydrogen bondMedicinal chemistryCrystallographyStereochemistryPhotochemistryMoleculeInorganic chemistryOrganic chemistryReceptorPhysicsAstronomyBiochemistryMagnetism in coordination complexesMetal complexes synthesis and propertiesMetal-Catalyzed Oxygenation Mechanisms