Photoinduced direct C–H cyanoalkylation of azauracils <i>via</i> electron donor–acceptor complex activation
Zhi‐Qiang Zhu, Xiaolong Huang, Xi Yang, Qianqian Xu, H. Surya Prakash Rao, Zhenzhen Xu, Zongbo Xie, Zhanggao Le
Abstract
Photoinduced direct electron transfer between azauracils and cycloketone oxime esters for C–H cyanoalkylation through a transiently assembled chromophore activation was developed.
Topics & Concepts
ChemistryAcceptorPhotochemistryElectron donorElectron acceptorElectronOrganic chemistryCatalysisPhysicsCondensed matter physicsQuantum mechanicsSynthesis and Biological EvaluationCatalytic C–H Functionalization MethodsSynthesis of Indole Derivatives