Spray-Coated Thin-Film Ni-Oxide Nanoflakes as Single Electrocatalysts for Oxygen Evolution and Hydrogen Generation from Water Splitting
Noor‐Ul‐Ain Babar, Khurram Saleem Joya
Abstract
Electrochemical water splitting is a key process in many electrochemical energy conversion and storage phenomena.Simple synthesis methods to make highly porous and active nanostructured catalytic materials with large electroactive surface areas are very important to implement waterto-fuel conversion schemes.Herein, ultrafine, transparent thin-film nickeloxide (NiO x ) nanoflakes are facilely synthesized following a simple spraycoating method from a solution-phase precursor.The NiO x nanoscale structures are grown on the FTO surface in the form of highly uniform smooth thin films.They are employed as promising bifunctional electrocatalysts for the overall water splitting process under alkaline conditions.During water oxidation catalysis, NiO x -SC/FTO initiates the oxygen evolution reaction (OER) at an overpotential of just 250 mV while generating current decade at just 300 mV and demonstrates well-balanced kinetics toward OER. 10 mA cm -2 current density remains persistent for many hours of continuous electrolysis at just 1.53 V RHE illustrating high robustness of the system.The catalyst also showed substantial activity and durability toward the hydrogen evolution reaction (HER) under the same electrochemical conditions.Tafel slopes of just 57 and 89 mV dec -1 for OER and HER in 0.5 M aqueous KOH solution, respectively, showing high intrinsic kinetics for electrocatalysis.Having high electrochemical surface area and an optimum number of electrochemically active sites, these transparent NiO x thin films can be advantageously combined with photoelectrochemical devices for light-driven water-to-fuel conversion systems.