Tuning the sensitization pathway T1→5DJ in Eu-based MOF through modification of the antenna ligand. A theoretical approach via multiconfigurational quantum calculations
Yoan Hidalgo‐Rosa, Julián Santoyo-Flores, Manuel A. Treto‐Suárez, Eduardo Schott, Dayán Páez-Hernández, Ximena Zárate
Topics & Concepts
PhosphorescenceAntenna effectChemistryLigand (biochemistry)SensitizationExcited stateIntersystem crossingLanthanideAntenna (radio)Multireference configuration interactionBenzoic acidIonPhotochemistryComputational chemistryFluorescenceLuminescenceAtomic physicsDensity functional theoryMaterials scienceComputer sciencePhysicsOptoelectronicsSinglet stateBasis setQuantum mechanicsTelecommunicationsOrganic chemistryImmunologyReceptorBiologyBiochemistryLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence Properties of Advanced Materials