Design Strategies of Flame-Retardant Additives for Lithium Ion Electrolyte
Zhenhai Gao, Shun Rao, Tianyao Zhang, Weifeng Li, Xiaoguang Yang, Yupeng Chen, Yadan Zheng, Yuhang Ding, Tingyue Dong, Songyu Li
Abstract
Abstract As the energy density of lithium-ion batteries continues to increase, battery safety issues characterized by thermal runaway have become increasingly severe. Battery safety issues have severely restricted the large-scale application of power batteries. Among them, the flammable liquid organic electrolyte is one of the main reasons for the safety hazards of battery thermal runaway. This article reviews the flame-retardant mechanism and research progress of phosphorus-based flame-retardant additives, nitrogen-based flame-retardant additives, and halogen-based flame-retardant additives. The design strategies of conventional flame-retardant additives and intelligent flame-retardant additives in lithium-ion batteries are summarized. Finally, a development direction and research prospects of flame-retardant additives in lithium-ion battery electrolytes are prospected.