Direct and continuous generation of pure acetic acid solutions via electrocatalytic carbon monoxide reduction
Peng Zhu, Chuan Xia, Chun-Yen Liu, Kun Jiang, Guanhui Gao, Xiao Zhang, Xia Yang, Yongjiu Lei, Husam N. Alshareef, Thomas P. Senftle, Haotian Wang
Abstract
, ultrahigh relative purity of up to 98 wt%, and excellent stability of over 150 h continuous operation. Density functional theory simulations reveal the role of stepped sites along the cube edge in promoting the acetate pathway. Additionally, a PSE layer, other than a conventional liquid electrolyte, was designed to separate cathode and anode for efficient ion conductions, while not introducing any impurity ions into generated liquid fuels. Pure acetic acid solutions, with concentrations up to 2 wt% (0.33 M), can be continuously produced by employing the acetate-selective Cu catalyst in our PSE reactor.