Simulating Chemistry on Bosonic Quantum Devices
Rishab Dutta, Delmar G. A. Cabral, Ningyi Lyu, Nam P. Vu, Yuchen Wang, Brandon Allen, Xiaohan Dan, Rodrigo G. Cortiñas, Pouya Khazaei, M. Schäfer, Alejandro Cros Carrillo de Albornoz, Scott E. Smart, Scott Nie, Michel Devoret, David A. Mazziotti, Prineha Narang, Chen Wang, James Whitfield, Angela K. Wilson, Heidi P. Hendrickson, Daniel A. Lidar, F. Pérez‐Bernal, Lea F. Santos, Sabre Kais, Eitan Geva, Victor S. Batista
Abstract
Bosonic quantum devices offer a novel approach to realize quantum computations, where the quantum two-level system ( qubit ) is replaced with the quantum (an)harmonic oscillator ( qumode ) as the fundamental building block of the quantum simulator. The simulation of chemical structure and dynamics can then be achieved by representing or mapping the system Hamiltonians in terms of bosonic operators. In this Perspective, we review recent progress and future potential of using bosonic quantum devices for addressing a wide range of challenging chemical problems, including the calculation of molecular vibronic spectra, the simulation of gas-phase and solution-phase adiabatic and nonadiabatic chemical dynamics, the efficient solution of molecular graph theory problems, and the calculations of electronic structure.