Pd-Oxazolone complexes conjugated to an engineered enzyme: improving fluorescence and catalytic properties
Carla Garcia‐Sanz, Alicia Andreu, Blanca de las Rivas, Ana I. Jiménez, Alexandra Pop, Cristian Silvestru, Esteban P. Urriolabeitia, José M. Palomo
Abstract
. Also the applicability of GTL-C114 conjugated with orthopalladated 4b in a site-selective C-H activation reaction under mild conditions has been demonstrated. Therefore, the Pd incorporation into the enzyme produces a highly stable conjugate, and improves remarkably the catalytic activity and selectivity, as well as the fluorescence intensity, of the Pd complexes.
Topics & Concepts
OxazoloneConjugated systemCatalysisEnzymeConjugateChemistryFluorescenceCombinatorial chemistryPhotochemistryOrganic chemistryPolymerMathematicsMathematical analysisPhysicsQuantum mechanicsSynthesis and Reactions of Organic CompoundsCyclopropane Reaction MechanismsFluorine in Organic Chemistry