Post-synthetic ligand cyclization in metal–organic frameworks through functional group connection with regioisomerism
Dasom Kim, Haneul Yoo, Kyunghwan Kim, Dongwook Kim, Ki Tae Kim, Cheoljae Kim, Jin Yeong Kim, Hoi Ri Moon, Min Kim
Abstract
Novel post-synthetic ligand cyclization (PSLC) strategy for metal–organic frameworks (MOFs) bearing regioisomeric functional groups has been developed to install benzo-fused heterocycles in MOFs.
Topics & Concepts
FormamideLigand (biochemistry)BenzoxazoleMetal-organic frameworkChemistryCovalent bondCombinatorial chemistryMetalConnection (principal bundle)Microwave irradiationFunctional groupOrganic chemistryPolymerReceptorBiochemistryAdsorptionEngineeringCatalysisStructural engineeringMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes