Mechanism of <i>N</i>,<i>N</i>-dimethylformamide electrochemical oxidation using a Ti/RuO<sub>2</sub>–IrO<sub>2</sub> electrode
Xuyang Hu, Hao Dong, Yinghao Zhang, Baihui Fang, Wenqiang Jiang
Abstract
DMF was performed under the optimal conditions; the degradation rate was 97.2% after 7 h, and the reaction followed the pseudo-first-order kinetic model. The degradation products under optimal conditions and chlorine-free conditions were analyzed, and four degradation pathways were proposed. The DMF degradation was more thorough under optimal conditions.
Topics & Concepts
ElectrochemistryElectrodeDimethylformamideMechanism (biology)ChemistryMaterials sciencePhysical chemistryInorganic chemistryPhysicsOrganic chemistryQuantum mechanicsSolventAdvanced oxidation water treatmentElectrochemical Analysis and ApplicationsOxidative Organic Chemistry Reactions