A general platform for phosphorylation reactions enabled by photoinduced palladium catalysis
Yujie Zhang, Xuesong Wang, Jian Cao, Li‐Wen Xu
Abstract
A photoinduced palladium-catalyzed generation of phosphorus radicals using Cl–phosphine oxides and Cl–phosphates is realized to achieve formal P-Heck reaction, C–H phosphinylation of heteroaromatics and difunctionalization of alkenes.
Topics & Concepts
PalladiumPhosphineCatalysisChemistryRadicalCombinatorial chemistryHeck reactionPhosphorusPhotochemistryOrganic chemistryCatalytic C–H Functionalization MethodsSulfur-Based Synthesis TechniquesOrganophosphorus compounds synthesis