Visible-light-mediated synthesis of polysubstituted pyrroles <i>via</i> C<sub>Ar</sub>–I reduction triggered 1,5-hydrogen atom transfer process
Junlei Wang, Qinglin Xie, Guocheng Gao, Guofen Wei, Xinxin Wei, Xue‐Mei Chen, Daohai Zhang, Hongqing Li, Binbin Huang
Abstract
A novel strategy for the construction of polysubstituted pyrroles has been developed through the visible-light-induced single-electron reduction of C Ar –I bonds and the following 1,5-hydrogen atom transfer (HAT) process.
Topics & Concepts
ChemistryHydrogen atomReduction (mathematics)Atom (system on chip)PhotochemistryHydrogenProcess (computing)Combinatorial chemistryOrganic chemistryAlkylParallel computingGeometryMathematicsOperating systemComputer scienceFluorine in Organic ChemistryRadical Photochemical ReactionsOxidative Organic Chemistry Reactions