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An Approach for Magnetic Halloysite Nanocomposite with Selective Loading of Superparamagnetic Magnetite Nanoparticles in the Lumen

Hady Hamza, Anna Maria Ferretti, Claudia Innocenti, Katarzyna Fidecka, Emanuela Licandro, Claudio Sangregorio, Daniela Maggioni

2020Inorganic Chemistry19 citationsDOIOpen Access PDF

Abstract

synthesis of SPION by thermal decomposition were not effective. HNT-TDP were characterized by infrared spectroscopy (ATR-FTIR), thermogravimetric analysis (TGA), and ζ-potential, and all of the techniques confirmed the presence of TDP onto the HNT. Moreover, the inner localization of TDP was ascertained by the use of Nile Red, a molecule whose luminescence is very sensitive to the polarity of the environment. The free SPION@OA (as a colloidal suspension and as a powder) and SPION-in-HNT powder were magnetically characterized by measuring the ZFC-FC magnetization curves as well as the hysteresis cycles at 300 and 2.5 K, confirming that the super-paramagnetic behavior and the main magnetic properties of the free SPION were preserved once embedded in SPION-in-HNT.

Topics & Concepts

HalloysiteSuperparamagnetismThermogravimetric analysisChemistryNanorodMagnetiteChemical engineeringNanocompositeTransmission electron microscopyNanoparticleFourier transform infrared spectroscopyMagnetic nanoparticlesNucleationNanotechnologyMagnetizationMaterials scienceOrganic chemistryMagnetic fieldPhysicsQuantum mechanicsMetallurgyEngineeringClay minerals and soil interactionsIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications
An Approach for Magnetic Halloysite Nanocomposite with Selective Loading of Superparamagnetic Magnetite Nanoparticles in the Lumen | Litcius