Mechanoresistive single-molecule junctions
Andrea Vezzoli
Abstract
which means that its electrical resistance/conductance changes upon application of a mechanical stress. The mechanoresistive phenomenon can arise at the metal-molecule interface or it can be embedded in the molecular backbone, and several strategies to attain high reproducibility, high sensitivity and reversible behaviour have been developed over the years. These devices offer a unique insight on the process of charge transfer/transport at the metal/molecule interface, and have potential for applications as nanoelectromechanical systems, integrating electrical and mechanical functionality at the nanoscale. In this review, the status of the field is presented, with a focus on those systems that proved to have reversible behaviour, along with a discussion on the techniques used to fabricate and characterise mechanoresistive devices.