Solvent-free synthesis of a new perfluorinated MIL-53(Al) with a temperature-induced breathing effect
Diletta Morelli Venturi, Virginia Guiotto, Roberto D’Amato, Lucia Calucci, Matteo Signorile, Marco Taddei, Valentina Crocellà, Ferdinando Costantino
Abstract
A new fluorinated member of the MIL-53(Al) family, displaying a unique temperature-induced phase transition, was synthesised via a solvent-free route.
Topics & Concepts
SolventPhase (matter)Phase transitionMaterials scienceChemical engineeringChemistryPolymer chemistryOrganic chemistryThermodynamicsPhysicsEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsInorganic Fluorides and Related CompoundsChemical Synthesis and Characterization