Merging radical-polar crossover/cycloisomerization processes: access to polyfunctional furans enabled by metallaphotoredox catalysis
Yongjun Liu, Wenping Luo, Tingting Xia, Yewen Fang, Chan Du, Xiaoping Jin, Yan Li, Li Zhang, Wan Lei, Hao Wu
Abstract
Metallaphotoredox catalysis for furan synthesis: The cyclisation of yne-enones proceeds smoothly <italic>via</italic> consecutive reductive radical-polar crossover and cycloisomerization processes enabled by cooperative photoredox-neutral and copper catalysis.
Topics & Concepts
CycloisomerizationChemistryFuranPolarCatalysisPhotoredox catalysisCrossoverPhotochemistryCombinatorial chemistryOrganic chemistryPhotocatalysisPhysicsAstronomyComputer scienceArtificial intelligenceRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods