High adsorption of ammonia in a titanium-based metal–organic framework
Xiangdi Zeng, Jiangnan Li, Meng He, Wanpeng Lu, Danielle Crawshaw, Lixia Guo, Yujie Ma, Meredydd Kippax‐Jones, Yongqiang Cheng, Pascal Manuel, Svemir Rudić, Mark D. Frogley, Martin Schröder, Sihai Yang⧫
Abstract
A robust titanium-based metal–organic framework, MFM-300(Ti), exhibits an exceptional NH 3 adsorption of 23.4 mmol g −1 with a record-high packing density of 0.84 g cm −3 , promoted by strong binding interactions of NH 3 to the framework oxygen sites.
Topics & Concepts
AdsorptionTitaniumAmmoniaMetal-organic frameworkMetalChemistryInorganic chemistryMaterials scienceChemical engineeringEnvironmental chemistryOrganic chemistryEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsAdsorption and biosorption for pollutant removalAmmonia Synthesis and Nitrogen Reduction