Chromium based metal–organic framework MIL-101 decorated palladium nanoparticles for the methanolysis of ammonia-borane
Nurdan Caner, Mehmet Yurderi, Ahmet Bulut, Gülşah Saydan Kanberoğlu, Murat Kaya, Mehmet Zahmakıran
Abstract
Pd@MIL-101 synthesized by a novel and facile approach acts as a highly active nanocatalyst (TOF = 1080 min<sup>−1</sup>) in the methanolysis of ammonia-borane (NH<sub>3</sub>BH<sub>3</sub>) under air at room temperature.
Topics & Concepts
ChemistryAmmonia boranePalladiumBoraneAmmoniaNanoparticleChromiumMetalInorganic chemistryNuclear chemistryCatalysisPolymer chemistryOrganic chemistryNanotechnologyHydrogen productionMaterials scienceMetal-Organic Frameworks: Synthesis and ApplicationsHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction